Process and device for cross-linked/expanding a blank for a safety support for a tire and support obtained by this process

ABSTRACT

A process for cross-linking/expanding at least one cross-linkable, expandable blank, which is intended to form all or part of an elastomeric safety support for a tire in which:  
     the cross-linking consists of curing the expandable or expanded blank in a bath of fluid at excess pressure which is contained in an enclosure, such that the blank interacts with the bath independently of the enclosure, the temperature of the bath having a maximum value of between 110° C. and 210° C. and the absolute pressure of said bath having at least a value equal to or greater than 14 bar, and  
     the expansion consists of curing the cross-linkable or cross-linked blank in the bath, the temperature of the bath having a maximum value of between 110° C. and 210° C., and the absolute pressure of the bath having at least a value equal to or greater than 5 bar and a final pressure-relief value substantially equal to 1 bar, for expanding the blank such that its increase in volume is unlimited with respect to the enclosure.

BACKGROUND OF INVENTION

[0001] The present invention relates to a process for expanding at leastone cross-linkable or cross-linked blank which is intended toconstitute, in the cross-linked, expanded state, all or part of anelastomeric safety support of cellular structure having closed cells,said support being intended to be mounted on a wheel rim within a tire.The invention also relates to a process for cross-linking and expandingsaid or each blank, a device for implementing said expansion orcross-linking/expansion process, and finally a section of cross-linked,expanded support and such a support which are obtained by this process.

[0002] The safety supports according to the invention can be used forequipping tires, for example, of machinery or vehicles of thetwo-wheeler, automobile or heavy-vehicle type.

[0003] The use of elastomeric safety supports having closed cells iswell-known for competition tires which are intended to travel on bumpycourses of the “cross-country rally” type.

[0004] These cellular supports, which are usually of substantially toricform, are supposed to permit travel following a significant drop inpressure over a distance which depends in particular on the more or lesssevere conditions characterizing this travel, for example, followingperforation of the tire.

[0005] Such supports are generally obtained by extruding across-linkable, expandable rubber composition which has been subjectedto thermomechanical working in order to obtain a blank, then bycross-linking and expanding the blank, the origin of the expansion beingthe thermal decomposition of a blowing agent which is initially presentin the rubber composition.

[0006] More precisely, in a first step of thermomechanical working, therubber composition, which comprises in particular a diene elastomer suchas butyl rubber (copolymer of isoprene and isobutylene), a reinforcingfiller such as carbon black, a blowing agent to permit later obtainingof the expanded cellular structure, and a cross-linking system, iskneaded.

[0007] In a third step, which is carried out in an oven, the blank thusobtained is preheated, to a temperature usually of between 70° C. and100° C.

[0008] In a fourth step, performed in a mold, at least partialcross-linking of the preheated blank is effected, at a temperatureusually of between 130° and 150° C.

[0009] In a fifth step, which is performed in an oven, the demoldedblank is subjected to expansion, at atmospheric pressure and at atemperature usually of between 130° C. and 150° C.

[0010] Thus a cross-linked, expanded support is obtained.

[0011] French patent specification FR-A-2 095 535 describes a processfor foaming and hardening an elastomeric filler material, such aspolyisoprene, dimethyl-methylvinyl polysiloxane or polybutadiene, withina mounted assembly formed of a previously-vulcanised tire which ismounted on a wheel rim. This filler material is intended to equip tiresintended for vehicles of the heavy-vehicle type, and the main objectdesired is to minimize the surface oxidation within the body of thevulcanised tire.

[0012] This object is achieved in that document by implementing aprocess consisting of heating in an oven the mounted assembly by meansof saturated steam at a temperature of approximately 149° C., theneither removing the mounted assembly from the oven or carrying outtherein a plurality of heating cycles followed by removal of the steamwithin the oven, in order to permit blowing of the filler material.

[0013] It will be noted that this mounted assembly is intended to forman enclosure of the mold type for the filler material which it contains,owing to the fact that the foam being blown presses on the wall of thismounted assembly.

[0014] It will also be noted that the foam which presses against thewall of the mounted assembly is the seat of local chemical reactions atthe location of this wall (rim or tire), which induces heterogeneity ofstructure of the foam which is finally formed.

[0015] The conventional cross-linking/expansion processes which use amold for cross-linking have one major drawback, which is linked to thedensity characteristics of the cross-linked, expanded supports which areobtained. In fact, the cross-linked, expanded supports which areobtained by these processes using a mold are generally characterized byan intermediate layer having a significantly higher density (usually ina ratio of 1.5) than that of the core or center of the support. There isshown diagrammatically in FIG. 5 appended to the present description aview in cross-section through such a support having, radially towardsthe inside of its outer surface (at the location of which there is asurface layer or skin A of the support), this intermediate layer B andsaid core C.

[0016] Now, experience shows that this density gradient is at the originof increased propagation towards the core of the support of thedeformations which are imposed on the latter when travelling at zeropressure, which results in likewise increased internal heating of thesupport, which may cause the destruction thereof within a relativelyshort period of travel.

SUMMARY OF THE INVENTION

[0017] The object of the present invention is to propose a process forexpanding at least one partially cross-linked blank which is intended toform, in the cross-linked, expanded state, all or part of an elastomericsafety support of cellular structure having closed cells, said or eachsupport being intended to be mounted on a wheel rim within a tire, whichmakes it possible to overcome the aforementioned disadvantage inrelation to the use of a mold for the cross-linking.

[0018] To this end, an expansion process according to the invention issuch that it consists of curing said or each blank in a bath of fluid atexcess pressure which is contained in an enclosure, the temperature ofsaid bath having a maximum value of between 110° C. and 210° C., and theabsolute pressure of said bath having at least a value equal to orgreater than 5 bar and a final pressure-relief value substantially equalto 1 bar, for expanding said or each blank such that the increase involume thereof is unlimited with respect to said enclosure.

[0019] According to one example of embodiment of the invention, thisexpansion process consists in varying, discretely or continuously, saidabsolute pressure of said fluid between a maximum value less than orequal to 26 bar and a value less than said maximum value.

[0020] According to the invention, this expansion process consists inusing a liquid fluid, such as water, or a gaseous fluid, such as hotair, steam or nitrogen, for curing said or each blank.

[0021] According to an optional characteristic of the invention, thisexpansion process consists of cooling said bath to a temperature lessthan or equal to 100° C. and to an absolute pressure of between 1 and 26bar, following the curing of said or each blank.

[0022] According to another characteristic of the invention, thisexpansion process consists of curing a plurality of blanks of linearand/or curved forms in said bath.

[0023] It will be noted that the supports or parts of supports thusobtained may have forms and dimensions which are variable according tothe desired applications.

[0024] The subject of the present invention is also a process forcross-linking and expanding at least one cross-linkable, expandableblank which is intended to form, in the cross-linked, expanded state,all or part of an elastomeric safety support of cellular structurehaving closed cells, said support being intended to be mounted on awheel rim within a tire.

[0025] This cross-linking and expansion process according to theinvention also makes it possible to overcome the aforementioned drawbackin relation to cross-linked, expanded supports, which drawback resultsfrom the use of a mold for the cross-linking, and it is such that:

[0026] said cross-linking consists of curing said or each expandable orexpanded blank in a bath of fluid at excess pressure which is containedin an enclosure, such that said or each blank interacts with said bathindependently of said enclosure, the temperature of said bath having amaximum value of between 110° C. and 210° C., and the absolute pressureof said bath having at least a value equal to or greater than 14 bar,and in that

[0027] said expansion consists of subjecting said or each cross-linkableor cross-linked blank to an expansion process according to the inventionsuch as defined above.

[0028] It will be noted that in the present description “cross-linkableblank” is understood to mean a blank which can still be cross-linked,independently of prior heat treatments which may have caused the startof cross-linking. Consequently, a blank which has previously beensubjected to heat treatment involving surface cross-linking is forexample considered as being cross-linkable. This heat treatment may haveconsisted of preheating in an oven of an extruded blank and/or in theoperation of forming a blank itself, in the event that it is injectionor transfer molding, for example, which is being effected.

[0029] It will also be noted that this cross-linking and expansionprocess according to the invention makes it possible to be set free fromthe toric geometry of the blank which is conventionally imposed by usinga mold, and that it also makes it possible to obtain cross-linked,expanded supports or parts of supports having complex geometries whichwould be difficult to demold under satisfactory conditions, such as forexample, grooves and/or lobes and/or cutouts in any one of thedirections of the support or the part of the support.

[0030] It will also be noted that this mold-less cross-linking/expansionoperation for cross-linking makes it possible to obtain supports orparts of supports which do not have a parting line, which does notweaken the corresponding support or part of the support.

[0031] According to one embodiment of the invention, this cross-linkingand expansion process may consist:

[0032] in a first step, of subjecting said or each cross-linkable,expandable blank to said cross-linking in order to obtain a practicallycross-linked, expandable blank, then

[0033] in a second step, of subjecting said or each blank which ispractically cross-linked and expandable which is obtained following saidfirst stage to said expansion, in order to obtain all or part of saidcorresponding cross-linked, expanded safety support.

[0034] According to another embodiment of the invention, thiscross-linking and expansion process may consist:

[0035] in a first step, of subjecting said or each cross-linkable,expandable blank to said expansion in order to obtain a cross-linkable,practically expanded blank, then

[0036] in a second step, of subjecting said or each blank which iscross-linkable and practically expanded to said cross-linking, in orderto obtain all or part of said corresponding cross-linked, expandedsafety support.

[0037] Advantageously, the cross-linking and expansion process accordingto the invention consists of using one or more blanks each of which arebased on a copolymer of isoprene and isobutylene (butyl rubber or IIR).

[0038] This elastomer has in particular reduced air permeability.

[0039] According to other examples of embodiment, there could also beused for the blank(s) the halogenated, in particular chlorinated orbrominated, versions of this copolymer (BIIR or CIIR rubbers, bromobutyland chlorobutyl rubbers respectively), copolymers of dienes and ofalpha-olefins, for example terpolymers of ethylene, propylene and adiene (EPDM), polychloroprene (CR), or also a blend of natural rubber(NR) and polybutadiene (BR) in substantially identical proportions.

[0040] According to one example of embodiment of the invention, a curingdevice according to the invention for implementing said cross-linkingand expansion process of the type comprising an enclosure which isprovided with at least one opening for the introduction and extractionof said or each blank, means for receiving said or each blank, means forfilling said enclosure with liquid or gaseous fluid, and heating andpressurization means for the fluid contained within said enclosure, inwhich said enclosure comprises:

[0041] an introduction compartment provided at its inlet with an openingfor introducing into said compartment a unit of cross-linkable,expandable blanks for the curing thereof, said introduction openingbeing provided with a means for shutting it off,

[0042] a curing compartment provided downstream of said introductioncompartment and provided at its inlet with a first mobile partition forallowing it to communicate with said introduction compartment, saidcuring compartment being intended to contain said heated, pressurisedfluid in order to obtain a unit of cross-linked, expandable blanks, and

[0043] an extraction compartment provided downstream of said curingcompartment and provided at its inlet with a second mobile partition forallowing it to communicate with said curing compartment and at itsoutlet with an opening to atmospheric pressure for obtaining a unit ofcross-linked, expanded blanks and their extraction from said enclosure,said extraction opening being provided with a means for shutting it off,

[0044] means for alternately transferring said fluid at excess pressurefrom said extraction compartment towards said introduction compartment,and from said introduction compartment towards said extractioncompartment.

[0045] It will be noted that these compartments make it possible tocross-link and expand units of blanks continuously, by includingautomated displacement of each unit within one and the same compartmentand/or from one compartment to another, owing to the aforementionedopenings and mobile partitions.

[0046] In fact, these partitions and openings, when in the closedposition, make it possible to form locks at the location of theintroduction and extraction compartments and, when said openings are inthe closed position and said partitions are in the open position, enableone or the other of said introduction and extraction compartments (whichis then filled with fluid) to form alternately a pressure balance withthe adjoining curing compartment which is itself continuously filledwith fluid.

[0047] It will also be noted that the total volume expansion of theblanks is obtained in said extraction compartment when the absolutepressure in this compartment is again made equal to atmospheric pressure(by means of said extraction opening, which is then in the openposition, thus forming a pressure balance with the ambient air).

[0048] It will furthermore be noted that this cross-linking/expansiondevice according to the invention may be advantageously integrated in anoverall process for manufacturing supports or sections of supports whichis implemented continuously, that is to say, directly downstream of theforming stations, for example by extrusion or by injection, and forpreheating the shaped blanks in an oven.

[0049] A curing device according to the invention may comprise anyautomated means suitable for controlling and checking parameters of theexpansion/cross-linking process, such as temperature, pressure and theflow rate of curing water.

[0050] According to another example of embodiment of the invention, acuring device for implementing said cross-linking and expansion process,which is of the type comprising an enclosure which is provided withmeans for the introduction and extraction of said or each blank, meansfor receiving said or each blank, means for filling said enclosure withliquid or gaseous fluid, and heating and pressurization means for thefluid contained within said enclosure,

[0051] is such that said enclosure is provided with a plurality ofreceiving means respectively provided to receive a plurality of blanks,said receiving means being mounted adjacent to each other on a conduitintended for filling said enclosure with fluid and extending into theinterior thereof.

[0052] According to another characteristic of this example ofembodiment, said enclosure comprises an outlet conduit connected tomeans for circulating said fluid towards said means for filling theenclosure.

[0053] According to another example of embodiment of the invention, acuring device for implementing said cross-linking and expansion process,of the type comprising an enclosure which is provided with at least oneopening for the introduction and extraction of said or each blank, meansfor receiving said or each blank, means for filling said enclosure withliquid or gaseous fluid, and heating and pressurization means for thefluid contained within said enclosure, is such that:

[0054] said means for filling the enclosure are formed of a conduitopening into an opening in said enclosure, said enclosure being providedwith a means which slides hermetically on the inner face of its wall forpressurising the fluid contained within said enclosure, this enclosurealso being suitable for permitting emptying of said enclosure, and that

[0055] said means for heating said fluid are mounted around saidenclosure and said conduit.

[0056] It will be noted that, in this example of embodiment, the slidingmeans for pressurising the interior of the enclosure may be of thepiston type, and that said heating means may for example comprise a coilthrough which a heat-transfer fluid flows, or an electrical resistor.

[0057] As for the fluid which can be used in this example of embodiment,it is preferably formed of a liquid, the boiling point of this liquidbeing beyond the temperature used for the curing, which may vary from110° C. to 210° C.

[0058] However, it is also possible to use a gas, provided that a gas isused, the relative weight of which relative to the air is suitable topermit the pressurization of said enclosure from said filling/emptyingconduit.

[0059] A section of safety support according to the invention, or such asafety support also according to the invention, are obtained by thecross-linking/expansion process referred to above, said section beingformed of a cross-linked, expanded rubber composition having a cellularstructure having closed cells.

[0060] Advantageously, these cross-linked, expanded sections or supportsaccording to the invention may each comprise, radially towards theinside of their outer surface, an intermediate layer, the thickness ofwhich is between 5% and 30% of the smallest dimension of a cross-sectionthrough said section or said support, and the density of which is lessthan that of the core of said section or said support.

[0061] It will be noted that this density gradient could not be obtainedby the aforementioned conventional processes, that is to say withcross-linking in a mold followed by expansion to atmospheric pressure.

[0062] This intermediate layer of low density makes it possible tominimize the internal heating of the support when travelling at zeropressure.

[0063] According to another characteristic of the invention, thecross-linked, expanded sections or supports obtained each have a maximumdensity in a surface layer at the location of their outer surfaces,radially to the outside of said intermediate layer.

[0064] It will be noted that this surface layer, which has a highdensity close to that of the corresponding non-expanded blank, impartsto the support or to the section of support a surface resistance whichis suited, firstly, to direct mounting on the rim and, secondly, to therepeated contacts with the reliefs of the inner face of a tire.

[0065] According to another characteristic of the invention, thecross-linked, expanded supports or sections obtained each have anaverage density of between 0.04 and 0.4 and, for example, substantiallyequal to 0.13.

[0066] It will be noted that an average density of close to 0.04 makesit possible to have a support characterized by satisfactory damping ofshocks and by minimized internal heating. Such a support is particularlyintended to be fitted on tires of the cross-country rally type fortemporary use.

[0067] An average density close to 0.4 makes it possible to impart highstructural rigidity to the corresponding support, which is particularlyintended to be fitted on tires bearing heavy loads.

[0068] As for an average density close to 0.13, it makes it possible toimpart to the core of the corresponding support sufficient rigidity, forexample to minimize the deformations of the support during travel whichare imposed by centrifuigal force, when the tire is under inflationpressure and when the base of the support is connected to the rim, forexample by means of a reinforcement or another means of connecting tothe rim. Such a support is particularly intended to be fitted on tiresof the automobile type.

[0069] According to another characteristic of the invention, therespective diameters of said cells vary on average from 0.1 mm to 2 mm,over a cross-section of said support or section.

[0070] Advantageously, said cross-linked, expanded section or supportare each based on a copolymer of isoprene and isobutylene.

[0071] According to one example of embodiment of the invention, saidcross-linked, expanded section or support each comprise, as reinforcingfiller, a blend of 10 to 30 phr silica and 10 to 30 phr carbon black(phr: parts by weight per hundred parts of elastomer(s)).

[0072] The silica which may be used may be any reinforcing silica knownto the person skilled in the art, in particular any precipitated orpyrogenic silica having a BET surface area and a CTAB specific surfacearea both of which are less than 450 m²/g, even if the highlydispersible precipitated silicas are preferred.

[0073] In the present specification, the BET specific surface area isdetermined in known manner, in accordance with the method of Brunauer,Emmett and Teller described in “The Journal of the American ChemicalSociety”, vol. 60, page 309, February 1938, and corresponding toStandard AFNOR-NFT-45007 (November 1987); the CTAB specific surface areais the external surface area determined in accordance with the sameStandard AFNOR-NFT-45007 of November 1987.

[0074] “Highly dispersible silica” is understood to mean any silicahaving a very substantial ability to disagglomerate and to disperse inan elastomeric matrix, which can be observed in known manner by electronor optical microscopy on thin sections. As non-limitative examples ofsuch preferred highly dispersible silicas, mention may be made forexample of the silica Ultrasil VN3 from Degussa, and the silicas Zeosil1165 MP and 1115 MP from Rhodia.

[0075] Of course, “silica” is also understood to mean mixtures ofdifferent silicas, in particular of highly dispersible silicas such asdescribed above.

[0076] Suitable carbon blacks are any carbon blacks, in particular theblacks of the type HAF, ISAF and SAF, which are conventionally used intires, and particularly in tire treads. As non-limitative examples ofsuch blacks, mention may be made of the blacks N115, N134, N234, N339,N347 and N375. The mass fraction of carbon black present in thereinforcing filler may vary within wide limits, this quantity preferablybeing from 40% to 60%, for a mass fraction of silica of from 60 to 40%.

[0077] According to one example of embodiment of the invention, thesupport or section of support, which comprises a base intended to bemounted on said wheel rim and a crown intended to bear on the tread ofsaid tire following a drop in pressure within the latter, is such thatit has at least one longitudinal groove extending over said crownsubstantially level with the latter, in the direction of the length ofsaid support or section of support.

[0078] According to another example of embodiment of the invention, thesupport or section of support is such that it has at least onelongitudinal cutout in its mass, which extends in the direction of thelength of said support or section of support.

[0079] It will be noted that these two examples of profiles of supportsor of sections of supports, which may be obtained using thecross-linking/expansion process according to the invention, cannot beobtained under satisfactory conditions by means of the conventionalprocesses using a mold for cross-linking. In fact, these particularprofiles make the demolding operation particularly difficult.

DESCRIPTION OF THE DRAWINGS

[0080] The aforementioned characteristics of the present invention, aswell as others, will be better understood on reading the followingdescription of several examples of embodiment of the invention, whichare given by way of illustration and not of limitation, said descriptionbeing given in relation to the appended drawing, in which:

[0081]FIG. 1 is a diagram illustrating an example of a device forimplementing the cross-linking/expansion process according to theinvention,

[0082]FIGS. 2 and 3 are diagrammatic sectional views illustratinganother embodiment of a curing device for implementing thecross-linking/expansion process according to the invention in twooperating positions.

[0083]FIG. 4 is a diagrammatic view in partial section of anotherembodiment of a curing device according to the invention forimplementing this process, and

[0084]FIG. 5 is a diagrammatic sectional view through a support obtainedby the cross-linking/expansion process according to the invention, and

[0085]FIGS. 6 and 7 show two embodiments of profiles of supportsaccording to the invention.

DESCRIPTION OF PREFERRED EMBODIMENTS

[0086] A curing device in accordance with FIG. 1 comprises an enclosure1 which is provided with at least one gate closable opening 2, 3 for theintroduction and extraction of units 4 comprising a plurality of blanks5 a, 5 b, means for receiving each blank, means for filling saidenclosure 1 with liquid or gaseous fluid 6, and heating andpressurization means for the fluid 6 contained within said enclosurewhich are controlled by control means (these receiving, filling,heating/pressurization and control means are not shown for reasons ofclarity).

[0087] The enclosure 1 of FIG. 1 comprises:

[0088] an introduction compartment 7 provided at its inlet with anopening 2 for introducing a unit 4 of cross-linkable, expandable blanks5 a, said introduction opening 2 being provided with a means 2 a forpermitting the freeing or blocking thereof (this opening 2 is shown inthe blocked position in FIG. 1),

[0089] a curing compartment 8 provided downstream of the previous oneand provided at its inlet with a first mobile partition 9 for placing itin communication with said introduction compartment 7 (this partition 9is shown in the hermetic partitioning position in FIG. 1). This curingcompartment 8 is intended to contain said fluid 6 which is heated andunder pressure in order to obtain at least one unit 4 of cross-linked,expandable blanks 5 b (in the simply illustrative example of FIG. 1, thecompartment 8 is intended to receive two units 4),

[0090] an extraction compartment 10 provided downstream from the former,which is intended to receive one unit 4 of said cross-linked, expandableblanks 5 b. This compartment 10 is provided at its inlet with a secondmobile partition 11 for placing it in communication with said curingcompartment 8 (this partition 11 is also shown in the hermeticpartitioning position in FIG. 1), and at its outlet with an opening 3for extracting from said enclosure 1 a unit 4 of cross-linked, expandedblanks 5 c, said extraction opening 3 (shown in the open position inFIG. 1) being provided with a means 3 a for freeing or blocking it; and

[0091] means 12 for alternately transferring the fluid 6 at excesspressure from the extraction compartment 10 towards the introductioncompartment 7, and vice versa (an element 12 a for setting the fluid 6in motion is shown in FIG. 1, for example a pump).

[0092] The cross-linking operation, which is carried out in the curingcompartment 8, consists of curing each unit 4 of cross-linkable,expandable blanks 5 a in a bath of fluid 6 at excess pressure, such thateach blank interacts with said bath 6 independently of the compartment8, the temperature of said bath 6 having a maximum value of between 110°C. and 210° C., and the absolute pressure of said bath 6 having at leasta value equal to or greater than 14 bar.

[0093] As for the expansion operation, it is initiated in the curingcompartment 8 during the cross-linking (the blowing agent present ineach blank 5a decomposing, which initiates the germination of thecells), but the expansion (in the conventional sense of increase involume, which is attributed to this term in the present description)effectively taking place only in the extraction compartment 10, when thelatter is devoid of the fluid 6 and is brought to atmospheric pressure.

[0094] More precisely, the temperature of said bath 6 in the curingcompartment 8 has a maximum value of between 110° C. and 210° C., andthe absolute pressure of said bath 6 has at least a value equal to orgreater than 5 bar.

[0095] Still in accordance with the invention, the expansion of eachcross-linked blank 5 b, which takes place at a final pressure-reliefvalue of the absolute pressure at 1 bar, is effected such that theincrease in volume of each blank 5 b is unlimited with respect to theextraction compartment 10, to produce the corresponding cross-linked,expanded support or part of the support 5 c.

[0096] This device can operate continuously, advantageously directlydownstream from the forming stations for the blanks (for exampleconsisting of extruders) and the stations for preheating the formedblanks in an oven, by reproducing over time the following cycle ofoperations.

[0097] There is extracted from the extraction compartment 10 a unit ofcross-linked, expanded supports or parts of supports 5 c of rank n, thenthe partition 11 is moved into the de-partitioning position in order tofill this compartment 10, the opening 3 of which has been blocked, withfluid 6, so as to be able to displace each unit 4 contained in theenclosure 1 by one rank. The unit of rank n+1 of cross-linked,expandable blanks 5 b is thus in said compartment 10, for the expansionthereof.

[0098] There is introduced in parallel a unit 4 of higher rank (n+3 inthe example of FIG. 1) into the introduction compartment 7, which haspreviously been open to atmospheric pressure, then the opening 3 of thecompartment 10 is blocked in order to transfer the fluid 6 contained inthe extraction compartment 10 to the compartment 7, as is indicated bythe arrow A of FIG. 1 (the partition 11 of the compartment 10 havingfirst been moved into the closed position).

[0099] Then the opening 3 of the compartment 10 is opened to permitexpansion of the blanks 5 b of the unit 4 of rank n+1, owing to theequilibrium at atmospheric pressure, then the cross-linked, expandedblanks 5 c of this unit are extracted.

[0100] In parallel, the units 4 are displaced within the enclosure 1 byone rank, as indicated previously, the pressure equalization between thecompartments 7 and 8, on one hand, and 8 and 10, on the other hand,making this displacement possible (the arrow B in FIG. 1 illustrates thetransfer of the fluid 6 from the compartment 7 to the compartment 10),and so on.

[0101] There is shown in FIGS. 2 and 3 another example of embodiment ofa curing device according to the invention for thecross-linking/expansion of a unit 4 of blanks 5 a.

[0102] This curing device comprises an opening 2 for the introduction ofa unit 4 of cross-linkable, expandable blanks 5 a (see FIG. 2) and forthe extraction of the corresponding unit 4 of the cross-linked, expandedsupports or parts of supports 5 c, which are shown in broken lines inFIG. 3 (at the end of the expansion operation). This device alsocomprises means for filling the enclosure 1 which are provided by aconduit 13 which communicates through an opening 14 with said enclosure1.

[0103] The conduit 13 is provided with a means 15 which slideshermetically on the inner face of its wall to pressurise the fluid 6contained within said enclosure 1 (see arrow C in FIG. 3, in which theopening 2 has been closed in order to fill the enclosure 1 with thefluid 6). This means 15 is for example of the piston type.

[0104] The fluid 6 which can be used in this embodiment is preferablyformed of a liquid, the boiling point of this liquid being above thetemperature used for the cross-linking/expansion, which may vary from110° to 210° C.

[0105] Furthermore, the conduit 13 is also suitable to permit emptyingof said enclosure 1.

[0106] This curing device also comprises means 16 for heating the fluid6 which are mounted around said enclosure 1 and said conduit 13. Theseheating means 16 may be formed of a coil through which a heat-transferfluid flows, or an electrical resistor.

[0107] Of course, the curing device of FIGS. 2 and 3 comprises means forreceiving the blanks 5 a in the enclosure 1, and also means forcontrolling the pressure and temperature parameters.

[0108] Another example of a curing device according to the invention isshown in FIG. 4.

[0109] This device is essentially formed of an enclosure 21 which isprovided with a fluid inlet conduit 23 (see arrow D) which opens ontothe inside of the enclosure 21 via its end 23 a, said conduit 23 beingconnected to a heating and pressurization circuit for the bath 6 offluid contained in the enclosure 21, and of a fluid outlet conduitseparate from said inlet conduit 23 (this heating/pressurization circuitand said outlet conduit are not shown).

[0110] Of course, this device also comprises means for introducingcross-linkable, expandable blanks 5 a into the enclosure 21, and forextracting the corresponding cross-linked, expanded supports or parts ofsupports 5 c.

[0111] In the example of embodiment of FIG. 4, the inlet conduit 23 issuitable for supporting, at regular height intervals, plates 25 whichare each intended to receive a blank 5 a, for thecross-linking/expansion thereof.

[0112] There are shown in FIG. 4 blanks 5 a of overall toric form, butit will be noted that each plate 25 could receive blanks 5 a of anyshape, for example linear, in order to obtain linear sections ofsupports instead of toric supports.

[0113] Each plate 25 is provided with means 26 for centering thecorresponding blank 5 a when it is put in position. In the example ofFIG. 4, these means 26 are formed of a positioning block around whichthe blank 5 a is intended to be positioned.

[0114] Each of the two examples of a device according to the inventionwhich have been described above, on one hand, in relation to FIGS. 2 and3 and, on the other hand, in relation to FIG. 4, operate as follows.

[0115] In the manner of what has been described in relation to FIG. 1,the cross-linking operation consists of curing the cross-linkable,expandable blanks 5 a in the bath 6 of fluid at excess pressure, suchthat each blank interacts with said bath 6 independently of the walls ofthe enclosure 1, 21. More precisely, the temperature of the bath 6 has amaximum value of between 110° C. and 210° C., and its absolute pressurecomprises at least a value equal to or greater than 14 bar.

[0116] As for the expansion operation, it is initiated in said bath 6provided that the temperature thereof comprises a maximum value ofbetween 110° C. and 210° C., and that its absolute pressure has at leasta value equal to or greater than 5 bar, and the increase in volume ofthe blank 5 a, which is a result of the expansion, takes place actuallyonce the latter is at atmospheric pressure by opening the enclosure 1,21 (see the supports 5 c in broken lines in FIGS. 3 and 4).

[0117] As has been indicated in relation to FIG. 1, it will be notedthat this expansion is unlimited with respect to the walls of theenclosure 1, 21.

[0118] As far as the curing device of FIG. 4 is concerned, it will benoted that curing in the bath 6 may be advantageously effected with acontinuous flow of fluid, owing to the permanent circulation of thefluid from said outlet conduit to said inlet conduit 23.

First Series of Tests for Cross-Linking/Expansion

[0119] A plurality of tests were carried out, using for the blanks twocross-linkable, expandable rubber compositions which are both based onbutyl rubber but which differ essentially from one another in that afirst composition A comprises a reinforcing filler formed of carbonblack, whereas a second composition B comprises a reinforcing fillermade of a blend of carbon black and silica.

[0120] Table I hereafter sets forth these essential differences. TABLE I(phr: parts by weight per hundred parts of elastomer). ConstituentsComposition A Composition B introduced into the mixer (amount in phr)(amount in phr) Carbon black N683 40 20 Silica “Zeosil 1165 MP” — 20Blowing agent: 13 13 (azobisformamide)

[0121] Each blank was prior to this preheated by means of hot air in anelectric oven without pressure, for a period of 70 minutes and at atemperature of 90° C.

[0122] The cross-linking/expansion operation was carried out using wateras curing fluid.

[0123] A device was used such as that described in relation to FIG. 4,such that the water circulation rate from said outlet conduit to saidinlet conduit 23 was maintained at 15 liters of water per minute.

[0124] In Table II below there are shown the specific operatingconditions which are relative to each test performed, before the finalpressure-relief of the inner space of the enclosure 21 to atmosphericpressure to effect the expansion of the cross-linked blanks.

[0125] With reference to an operating stage of predetermined duration(in minutes), there are indicated the corresponding values of relativepressure in the enclosure 21 (in bar) and of temperature (in ° C.). Thesame applies to the final cooling step.

[0126] As far as the emptying of the enclosure 21 is concerned, whichmakes it possible to make the pressure within the latter pass from anexcess pressure value to the final pressure-relief value in order toeffect the expansion of the cross-linked blanks (atmospheric pressure),the rate of emptying is controlled such that the change from saidultimate excess pressure value to atmospheric pressure is effected in asufficiently long time, which in the tests performed is at least 30seconds. TABLE II Cross- linkable, blank first stage second stagecooling expandable length (bar, min., (bar, min., (bar, min., Testcomposition (mm) ° C.) ° C.) ° C.) No. 1 A 412 12 - 90 - 142 — 12 - 20 -20 No. 2 A 355 23 - 90 - 142 — 23 - 20 - 20 No. 3 A 275 23 - 50 - 142 —23 - 10 - 20 No. 4 A 275 16 - 90 - 142 — 16 - 20 - 20 No. 5 A 275 23 -60 - 142 9 - 40 - 142 9 - 20 - 20 No. 6 A 275 16 - 90 - 142 9 - 40 - 1429 - 20 - 20 No. 7 A 275 23 - 60 - 142 12 - 40 - 142 9 - 20 - 20 No. 8 B275 23 - 60 - 142 9 - 40 - 142 9 - 20 - 20

[0127] The supports obtained by means of these tests were analysed.Table III hereafter summarises the dimensional and cellularcharacteristics of the supports obtained.

[0128] Each of these cross-linked, expanded supports is characterized,on one hand, by an intermediate layer B of a thickness of several mmradially towards the inside of its outer surface and, on the other hand,by a surface layer A at the location of said external surface (see FIG.5).

[0129] As far as the measurement of the size of cells in the centrallayer C of each support is concerned, the sizes at the core and atmid-thickness were distinguished.

[0130] As far as the measurement of the size of cells in theintermediate layer B is concerned (last column of Table III), these aremeasurements of maximum sizes at 5 mm from the outer surface (surfacelayer A) of each support. TABLE III maximum maximum maximum Cross-diameters diameters of diameters linked, of the the cells at of thecells expanded width height cells at the mid-thickness in the layersupports (mm) (mm) core (mm) (mm) B (mm) No. 1 115 63 not measured notmeasured not measured (2 165 110 supports produced) No. 2 182 123.5 0.20.2 0.3-0.5 No. 3 105 50 not measured not measured not measured No. 4190 130 0.3 0.3 0.5 No. 5 193 106 0.5 0.5 0.5 No. 6 197 111 1   1   0.7No. 7 192 121 0.3 0.3 0.4 No. 8 208 118 1.8 1.3 0.7

[0131] The support obtained by test No. 1 has insufficientcross-linking, owing to the insufficient value of the pressure which isused, which value is not in accordance with the invention (12 barsrelative pressure).

[0132] The support obtained by test No. 2, which corresponds to the useof a relative pressure of 23 bar in the enclosure (maximum value usedfor all the tests), has a cell size in accordance with the invention(since it is between 0.1 and 2 mm).

[0133] The support obtained by test No. 3 has insufficient cross-linkingand expansion, owing to too short a dwell time in the curing bath, thisinsufficient expansion resulting from the premature stopping of thedecomposition reaction of the blowing agent.

[0134] It will be understood that an increase in the dwell time of theblank in the curing bath would have made it possible, in particular, toimpart increased expansion to a support, such as the one obtained intest No. 3, for example.

[0135] The support obtained by test No. 4 (using a single stage at therelative pressure of 16 bar) has satisfactory cross-linking andexpansion, and also a cell size in accordance with the invention.

[0136] The support obtained by test No. 5 (using two stages, therelative pressure values of which are 23 bar and 9 bar respectively)also has satisfactory cross-linking and expansion.

[0137] The support obtained by test No. 6 (using two stages, therelative pressure values of which are 16 bar and 9 bar respectively) hasincreased expansion compared with that of the preceding support (testNo. 5), as shown by the cell size, which has substantially doubled.

[0138] The support obtained by test No. 7 (using two stages, therelative pressure values of which are 23 bar and 12 bar respectively)also has satisfactory cross-linking and expansion characteristics.

[0139] As for the support obtained by test No. 8, which supportcomprises a blend of carbon black and silica as reinforcing filler, italso has satisfactory cross-linking and expansion. Furthermore, thisexpansion is very high in the core of the support.

[0140] It will be noted that each of the supports obtained by theprocess according to the invention is characterized by cell diameterswhich are relatively close to each other, from the core to the surfaceof the supports. Furthermore, it was confirmed that the intermediatelayer B of each support according to the invention was of a thicknessless than that of the known supports obtained by conventional processes,and that this layer B had an overall lower density than that of thecorresponding layer B of such a known support.

[0141] It will also be noted that the average cell size over across-section of the support is highest when the relative pressures ofthe first and second stages are respectively 16 bar and 9 bar (test No.6), whereas on the other hand it is lowest when a single stage ofrelative pressure of 23 bar is used (test No. 2).

Second Series of Tests for Cross-Linking/Expansion

[0142] A plurality of tests according to the invention were carried out,using for the blanks 4 rubber compositions comprising said compositionsA and B and two other cross-linkable, expandable compositions C and D,which are all based on butyl rubber.

[0143] Table IV hereafter gives the respective formulations of thesecompositions C and D. TABLE IV (phr: parts by weight per hundred partsof elastomer). Constituents Composition C Composition D introduced intothe mixer (amount in phr) (amount in phr) Carbon black N683 40 40 Silica“Zeosil 1165 MP” — — Blowing 12 11 agent(azobisformamide)

[0144] Each blank was prior to this preheated by means of hot air in aventilated oven, for a period of 70 minutes and at a temperature ofabout 100° C.

[0145] The cross-linking/expansion operation, as previously, is effectedby means of a continuous flow of water, by means of a device such asthat of FIG. 4, such that the circulation and emptying rates (for thecross-linking and the expansion, respectively) are maintained at 15liters of water per minute.

[0146] In Table V below there are shown the specific operatingconditions which relate to each test performed, before effecting thefinal pressure-relief of the inner space of the enclosure 21 toatmospheric pressure to effect the expansion of the cross-linked blanks.

[0147] With reference to an operating stage of predetermined duration(in minutes), there are indicated the corresponding values of pressure(in bar) and of temperature (in ° C.). The same applies to the finalcooling step. TABLE V Cross- linkable, blank blank first stage secondstage cooling expandable perimeter weight (bar, min., (bar, min., (bar,min., Test comp. (mm) (g) ° C.) ° C.) ° C.) No. 9 A 871 2785 23 - 95 -142 23 - 15 - 20 No. 10 A 868 2738 23 - 55 - 146 No. 11 A 859 2755 23 -60 - 142 12 - 50 - 142 12 - 20 - 20 No. 12 A 870 2782 23 - 60 - 142 9 -40 - 142 9 - 20 - 20 No. 13 A 856 2748 16 - 60 - 142 9 - 50 - 142 9 -20 - 20 No. 14 A 872 2778 16 - 60 - 142 12 - 40 - 142 12 - 20 - 20 No.15 A 867 2768 23 - 60 - 142 9 - 40 - 142 9 - 20 - 20 No. 16 A 873 276823 - 60 - 142 9 - 40 - 142 9 - 20 - 20 No. 17 A 869 2728 16 - 60 - 14212 - 50 - 142 No. 18 A 856 2754 23 - 30 - 142 12 - 40 - 142 12 - 20 - 20No. 19 A 866 2763 23 - 60 - 142 9 - 40 - 142 9 - 20 - 20 No. 20 A 8682768 23 - 60 - 142 9 - 40 - 142 9 - 20 - 20 No. 21 A 869 2772 23 - 60 -142 9 - 40 - 142 9 - 20 - 20 No. 22 A 867 2784 23 - 30 - 142 12 - 80 -142 12 - 20 - 20 No. 23 D 876 2765 23 - 60 - 142 9 - 40 - 142 9 - 20 -20 No. 24 C 976 1140 23 - 30 - 146 9 - 30 - 146 9 - 10 - 20 No. 25 C 9821144 23 - 30 - 146 9 - 40 - 146 9 - 20 - 20 No. 26 B 814 2726 23 - 60 -142 9 - 60 - 142 9 - 20 - 20 No. 27 B 848 2746 23 - 60 - 142 9 - 50 -142 9 - 20 - 20 No. 28 B 865 2738 23 - 60 - 142 9 - 60 - 142 9 - 20 - 20

[0148] The supports obtained by means of these tests were analyzed.Table VI hereafter summarises the dimensional and cellularcharacteristics of these supports.

[0149] The volumes of the cross-linked, expanded supports obtained weredetermined using a form factor of 0.8 (actual cross-section of thesupport/rectangular section in which this actual cross-section iscircumscribed). TABLE VI Cross- weight linked, of outer inner expandedsupport perimeter perimeter width Volume Average supports (g) (mm) (mm)(mm) (liters) density No. 9 2755 1907 1110 170 26.489 0.104 No. 10 2708— — — — — No. 11 2725 2007 1275 178 28.362 0.096 No. 12 2752 2018 1300178 28.212 0.098 No. 13 2718 1987 1230 175 28.024 0.097 No. 14 2748 19781190 163 26.211 0.105 No. 15 2738 2002 1295 181 28.212 0.097 No. 16 27382028 1320 185 29.414 0.093 No. 17 2698 2050 1225 177 31.024 0.087 No. 182724 1975 1236 183 28.885 0.094 No. 19 2733 2022 1300 180 28.749 0.095No. 20 2738 2060 1345 182 29.602 0.092 No. 21 2742 2048 1330 184 28.8460.092 No. 22 2754 1975 1203 173 27.757 0.099 No. 23 2735 1800 1200 17120.905 0.131 No. 24 1110 2005 1455   87.5 10.085 0.110 No. 25 1114 20331474  89 10.574 0.105 No. 26 2696 1850 1020 170 26.034 0.104 No. 27 27161900 1200 173 24.964 0.109 No. 28 2708 1942 1185 160 24.500 0.111

[0150] It will be noted that the average density of a cross-linked,expanded support according to the invention may vary to a great extentbetween 0.04 and 0.4, average densities close to 0.04 or 0.4 possiblybeing obtained respectively in a manner known to the person skilled inthe art by increasing or reducing the amount of blowing agent in thecorresponding rubber composition.

[0151] It will also be noted that the average density close to 0.13which was obtained, for example, by test No. 23 makes it possible toimpart to the core of the corresponding support a rigidity which issuitable for minimizing its deformation during travel owing tocentrifugal force.

[0152] The results of volume of the support which are mentioned in thisTable VI show that supports Nos. 11 to 28 have satisfactorycross-linking and expansion, this expansion being promoted by the secondstage of pressure at 9 or 12 bar (following a first stage at 23 or 16bar which permits cross-linking).

[0153] It was also possible to confirm that each support according tothe invention is characterized by cell diameters which are very close toeach other, from the core to the surface of the supports.

[0154] Furthermore, it was confirmed that the intermediate layer B ofeach support according to the invention has a thickness of less than 5mm, contrary to those of conventional supports, which are generallybetween 8 and 25 mm (for supports of width and height close to 200 mmand 120 mm, respectively), which makes it possible to minimize thepropagation in the core of the support of the deformations due to theshearing stresses and, consequently, the internal heating of the latterwhen travelling at zero pressure.

[0155] There are shown in FIGS. 6 and 7 two examples of embodiment ofprofiles of cross-linked, expanded supports which can be obtained by thecross-linking/expansion process according to the invention, that is tosay, by a process making it possible to dispense with a mold for thecross-linking.

[0156] According to the embodiment of FIG. 6, the support 5 c obtainedcomprises a base 30 which is intended to be mounted on a wheel rimeither directly, or by means of a reinforcement or another connectingagent, and a crown 31 which is intended to bear on a tread of a tire,following a drop in pressure within the latter.

[0157] This support 5 c has in this example a plurality of longitudinalgrooves 32 extending over the crown 31, substantially level with thelatter and in the direction of the length of the support 5 c.

[0158] It will be noted that the process according to the invention alsomakes it possible to obtain profiles of supports 5 c which have, inaddition to said single grooves 32, other longitudinal grooves (notshown) in at least one of the other two directions of the support 5 c(for example grooves on the face 33 of the support connecting the base30 and the crown 31 together).

[0159] According to the embodiment of FIG. 7, the support 5 c obtainedhas between its base 40 and its crown 41 a longitudinal cutout 42 in itsmass, which extends in the direction of its length.

[0160] It will be noted that these two examples of profiles of supportscould not be obtained under satisfactory conditions by means of theconventional processes using a mold for cross-linking, because theirrespective geometries do not permit demolding under satisfactoryconditions, that is to say, without weakening the demolded support.

We claim:
 1. A process for expanding at least one partially cross-linked blank which is intended to form, in the cross-linked, expanded state, all or part of an elastomeric safety support of cellular structure having closed cells, said support being intended to be mounted on a wheel rim within a tire, comprising curing said or each blank in a bath of fluid at excess pressure which is contained in an enclosure, the temperature of said bath having a maximum value of between 110° C. and 210° C., and the absolute pressure of said bath having at least a value equal to or greater than 5 bar and a final pressure-relief value substantially equal to 1 bar, for expanding said or each blank such that the increase in volume thereof is unlimited with respect to said enclosure.
 2. An expansion process according to claim 1, including varying, discretely or continuously, said absolute pressure of said fluid between a maximum value less than or equal to 26 bar and a value less than said maximum value.
 3. An expansion process according to claim 1, including using a liquid fluid for curing said or each blank.
 4. An expansion process according to claim 1 including using a gaseous fluid for curing said or each blank.
 5. An expansion process according to claim 1, including cooling said bath to a temperature less than or equal to 100° C. and at an absolute pressure of between 1 and 26 bar, following the curing of said or each blank.
 6. An expansion process according to claim 1, including curing in said bath a plurality of blanks of linear and/or curved forms.
 7. A process for cross-linking and expanding at least one cross-linkable, expandable blank which is intended to form, in the cross-linked, expanded state, all or part of an elastomeric safety support of cellular structure having closed cells, said support being intended to be mounted on a wheel rim within a tire, in which said cross-linking includes curing said or each expandable or expanded blank in a bath of fluid at excess pressure which is contained in an enclosure, such that said or each blank interacts with said bath independently of said enclosure, the temperature of said bath having a maximum value of between 110° C. and 210° C., and the absolute pressure of said bath having at least a value equal to or greater than 14 bar, and said expansion includes subjecting said or each cross-linkable or cross-linked blank to an expansion process according to claim
 1. 8. A cross-linking and expansion process according to claim 7, characterized in that it includes: in a first step, subjecting said or each cross-linkable, expandable blank to said cross-linking in order to obtain a practically cross-linked, expandable blank, then in a second step, subjecting said or each blank which is practically cross-linked and expandable following said first stage of said expansion, in order to obtain all or part of said corresponding cross-linked, expanded safety support.
 9. A cross-linking and expansion process according to claim 7, characterized in that it includes: in a first step, subjecting said or each cross-linkable, expandable blank to said expansion in order to obtain a cross-linkable, practically expanded blank, then in a second step, subjecting said or each blank which is cross-linkable and practically expanded to said cross-linking, in order to obtain all or part of said corresponding cross-linked, expanded safety support.
 10. A curing device for implementing the cross-linking and expansion process according to claim 7, the device comprising an enclosure which is provided with at least one opening for the introduction and extraction of said or each blank, means for receiving said or each blank, means for filling said enclosure with liquid or gaseous fluid, and heating and pressurization means for the fluid contained within said enclosure, characterized in that said enclosure comprises: an introduction compartment provided at its inlet with an opening for introducing into said compartment a unit of cross-linkable, expandable blanks for the curing thereof, said introduction opening being provided with a means for closing it, a curing compartment provided downstream of said introduction compartment and provided at its inlet with a first mobile partition for allowing it to communicate with said introduction compartment, said curing compartment being intended to contain said heated, pressurized fluid in order to obtain a unit of cross-linked, expandable blanks, and an extraction compartment downstream of said curing compartment and provided at its inlet with a second mobile partition for allowing it to communicate with said curing compartment and at its outlet with an opening to atmospheric pressure for extracting a unit of cross-linked, expanded blanks from said enclosure, said extraction opening being provided with a means for closing it, and means for alternately transferring said fluid at excess pressure from said extraction compartment towards said introduction compartment, and from said introduction compartment towards said extraction compartment.
 11. A curing device for implementing the cross-linking and expansion process according to claim 7, the device comprising an enclosure which is provided with means for the introduction and extraction of said or each blank, a means for receiving said or each blank, means for filling said enclosure with liquid or gaseous fluid, and heating and pressurization means for the fluid contained within said enclosure, characterized in that said enclosure is provided with a plurality of receiving means mounted adjacent each other on a conduit intended for filling said enclosure with fluid and extending into the interior thereof.
 12. A curing device according to claim 11, characterized in that said enclosure comprises an outlet conduit connected to means for circulating said fluid to said means for filling the enclosure.
 13. A curing device for implementing the cross-linking and expansion process according to claim 7, the device comprising an enclosure which is provided with at least one opening for the introduction and extraction of said or each blank, means for receiving said or each blank, means for filling said enclosure with liquid or gaseous fluid, and heating and pressurization means for the fluid contained within said enclosure, characterized in that said means for filling the enclosure are formed of a conduit opening into an opening in said enclosure, said conduit being provided with a means which slides hermetically on an inner face of a wall of said conduit for pressurizing the fluid contained within said enclosure, this conduit also permitting emptying of said enclosure, and in that said means for heating said fluid are mounted around said enclosure and said conduit.
 14. A safety support for a tire or section of said support obtained by a process according to claim 7, said support or said section being formed of a cross-linked, expanded rubber composition having a cellular structure having closed cells, said support being intended to be mounted on a wheel rim within a tire, characterized in that it comprises, radially towards the inside of its outer surface, an intermediate layer, the thickness of which is between 5% and 30% of the smallest dimension of a cross-section through said section and a core and in which the density of the intermediate layer is less than that of the core.
 15. A support or section of said support according to claim 14, characterized in that it has a maximum density in a surface layer at the location of its outer surface, radially to the outside of said intermediate layer.
 16. A support or section of said support according to claim 14, characterized in that it has an average density of between 0.04 and 0.4.
 17. A support or section of said support according to claim 16, characterized in that it has an average density substantially equal to 0.13.
 18. A support or section of said support according to claim 14, characterized in that the respective diameters of said cells vary on average from 0.1 mm to 2 mm over a cross-section of said support or section.
 19. A support or section of said support according to claim 14, characterized in that it consists of one or more blanks each of which are based on a copolymer of isoprene and isobutylene.
 20. A support or section of said support according to claim 14, characterized in that it comprises, as reinforcing filler, a blend of 10 to 30 phr silica and 10 to 30 phr carbon black (phr: parts by weight per hundred parts of elastomer(s)).
 21. A support or section of said support according to claim 14, comprising a base intended to be mounted on a wheel rim and a crown intended to bear on the tread of said tire following a drop in pressure within the tire, characterized in that it has at least one longitudinal groove extending over said crown substantially level with the latter, in the direction of the length of said support or section of support.
 22. A support or section of said support according to claim 14, characterized in that it has at least one longitudinal cutout in its mass, which extends in the direction of the length of said support or section of support.
 23. A support according to claim 14, characterized in that it is substantially in the form of a torus.
 24. A section of a support according to claim 14, characterized in that it is substantially in the form of a portion of a torus.
 25. A section of a support according to claim 14, characterized in that it is substantially of linear form. 